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王世怡,李一鸣. LED光源作用下的光催化染料降解研究[J]. 应用技术学报,2023,23(3):200-207.. DOI: 10.3969/j.issn.2096-3424.2023.03.003
引用本文: 王世怡,李一鸣. LED光源作用下的光催化染料降解研究[J]. 应用技术学报,2023,23(3):200-207.. DOI: 10.3969/j.issn.2096-3424.2023.03.003
WANG Shiyi, LI Yiming. Research on the application of LED light source in photocatalytic wastewater treatment technology[J]. Journal of Technology, 2023, 23(3): 200-207. DOI: 10.3969/j.issn.2096-3424.2023.03.003
Citation: WANG Shiyi, LI Yiming. Research on the application of LED light source in photocatalytic wastewater treatment technology[J]. Journal of Technology, 2023, 23(3): 200-207. DOI: 10.3969/j.issn.2096-3424.2023.03.003

LED光源作用下的光催化染料降解研究

Research on the application of LED light source in photocatalytic wastewater treatment technology

  • 摘要: 光催化处理染料类废水处理具有绿色、无二次污染的特点,但其在可见光下较低的处理速率以及人工光源较高的电能成本限制了该技术在工业上的推广。近年来随着发光二极管(LED)技术的不断发展,LED的光电转换效率不断提高,采用LED作为光催化污水处理中的光源或许是一种有效的手段,与传统的光源相比,其具有更小的体积、更长的寿命、更低的能耗和更强的可调性等优点。通过结合LED光源和光敏催化材料,可以实现高效、绿色的光催化反应。采用平行光反应器测试几种常见的光催化剂的光催化速率,并探究了LED的波长、辐照强度以及辐照方式对光催化速率的影响。研究表明TiO2在365 nm的光源照射下具有最高的一阶反应速率常数,g-C3N4在365~420 nm的波段中均具有相对较高的一阶反应速率常数,辐照强度以及方式的改变均有助于光催化速率的提升。

     

    Abstract: Photocatalytic dye wastewater treatment has the advantages of being green and free from secondary pollution. However, the low processing rate in visible light and the high electric energy cost of artificial light sources limit its implementation in industry. With the continuous development of light-emitting diode (LED) technology in recent years, the photoelectric conversion efficiency of LEDs has been constantly improved. Therefore, using LED as the light source for photocatalytic wastewater treatment may be an effective method to improve the efficiency of wastewater treatment. Compared to traditional light sources, LED technology has advantages such as smaller volume, longer service life, lower energy consumption and greater adjustability. By combining LED light sources with photosensitive catalysts, efficient and environmentally friendly photocatalytic reactions can be achieved. In this study, several common photocatalysts were tested for their photocatalytic rates using a parallel light reactor. The effects of LED wavelength, irradiance intensity and mode on photocatalytic rates were also investigated. The results showed that TiO2 had the highest first-order reaction rate constant under 365 nm LED irradiation, while g-C3N4 exhibited relatively high first-order reaction rate constants in the 365-420 nm wavelength range. Increasing irradiance intensity and the changes of irradiance mode were found to be conducive to improving the photocatalytic rate.

     

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