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金敏, 胡皓阳, 刘柱, 徐静涛, 江浩川, 蒋俊. Te自助熔剂定向凝固法生长CdTe晶体[J]. 应用技术学报, 2020, 20(3): 205-210. DOI: 10.3969/j.issn.2096-3424.2020.03.001
引用本文: 金敏, 胡皓阳, 刘柱, 徐静涛, 江浩川, 蒋俊. Te自助熔剂定向凝固法生长CdTe晶体[J]. 应用技术学报, 2020, 20(3): 205-210. DOI: 10.3969/j.issn.2096-3424.2020.03.001
JIN Min, HU Haoyang, LIU Zhu, XU Jingtao, JIANG Haochuan, JIANG Jun. Growth of CdTe Crystal via A Te Self-Flux Directional Solidification Method[J]. Journal of Technology, 2020, 20(3): 205-210. DOI: 10.3969/j.issn.2096-3424.2020.03.001
Citation: JIN Min, HU Haoyang, LIU Zhu, XU Jingtao, JIANG Haochuan, JIANG Jun. Growth of CdTe Crystal via A Te Self-Flux Directional Solidification Method[J]. Journal of Technology, 2020, 20(3): 205-210. DOI: 10.3969/j.issn.2096-3424.2020.03.001

Te自助熔剂定向凝固法生长CdTe晶体

Growth of CdTe Crystal via A Te Self-Flux Directional Solidification Method

  • 摘要: 碲化镉(CdTe)晶体是一种制造室温X射线和γ射线探测器最为理想的半导体材料,在医学、食品、安检、核废料监测等应用领域前景广阔。采用一种Te自助溶剂定向凝固技术生长CdTe晶体,在区熔温场及坩埚旋转系统的综合作用下,获得了平坦状的理想固液界面形貌。生长∅25 mm的CdTe晶体横截面单晶区域面积可达70%,从∅56 mm的CdTe晶体中可截取尺寸达15 mm×15 mm×3 mm的单晶,电学测试表明CdTe晶体在未掺杂改性条件下电阻率达108 Ω·cm。红外透射显示,CdTe晶体中包含尺寸范围为1~20 μm的Te夹杂,这是CdTe单晶生长过程中出现的主要微观缺陷。该工作取得的相关成果对未来CdTe晶体生长技术发展具有一定参考价值和借鉴意义。

     

    Abstract: Cadmium telluride (CdTe) crystal is one of the most ideal semiconductor materials for making room temperature X-ray and γ ray detectors, which has a wide application prospect in medicine, food, security inspection, nuclear waste monitoring and other fields. A Te self-flux directional solidification technology was proposed to grow CdTe crystal. Under the combined action of zone melting temperature field and crucible rotating system, the ideal solid-liquid interface morphology with micro bulge or flat shape was obtained. The single crystal area in the cross section of 25 mm CdTe crystal can reach 70%, and the single crystal with the size of 15 mm×15 mm×3 mm can be cut from the ∅56 mm CdTe crystal. Electrical test shows the CdTe crystal has excellent electrical properties under the condition of undoped modification, and the resistivity is up to 108 Ω·cm. The infrared transmission analysis shows that CdTe crystal contains Te inclusions with a size range of 1-20 μm, which is the main micro defect in the growth process. The results obtained have certain reference value and significance for the future development of CdTe crystal growth technology.

     

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