高级检索
王雅荣,房诗玉,房永征,等. 碲镉汞与钙钛矿量子点薄膜异质结的界面电子态及其荧光特性[J]. 应用技术学报,2022,22(3):189-197.. DOI: 10.3969/j.issn.2096-3424.2022.03.001
引用本文: 王雅荣,房诗玉,房永征,等. 碲镉汞与钙钛矿量子点薄膜异质结的界面电子态及其荧光特性[J]. 应用技术学报,2022,22(3):189-197.. DOI: 10.3969/j.issn.2096-3424.2022.03.001
WANG Yarong, FANG Shiyu, FANG Yongzheng, SUN Changhong, YE Zhenhua, LIU Yufeng. Study on Interface Electronic States and Fluorescence Properties on Heterostructures of HgCdTe and Perovskite Quantum Dot Films[J]. Journal of Technology, 2022, 22(3): 189-197. DOI: 10.3969/j.issn.2096-3424.2022.03.001
Citation: WANG Yarong, FANG Shiyu, FANG Yongzheng, SUN Changhong, YE Zhenhua, LIU Yufeng. Study on Interface Electronic States and Fluorescence Properties on Heterostructures of HgCdTe and Perovskite Quantum Dot Films[J]. Journal of Technology, 2022, 22(3): 189-197. DOI: 10.3969/j.issn.2096-3424.2022.03.001

碲镉汞与钙钛矿量子点薄膜异质结的界面电子态及其荧光特性

Study on Interface Electronic States and Fluorescence Properties on Heterostructures of HgCdTe and Perovskite Quantum Dot Films

  • 摘要: 半导体异质结是有源光电子器件最重要的材料组成部分之一。构筑了窄带隙半导体碲镉汞(Hg0.7Cd0.3Te)和宽带隙CsPbBr3半导体量子点薄膜的异质结,通过研究发现量子点与碲镉汞薄膜形成了Type-I异质结,CsPbBr3钙钛矿量子点薄膜中的部分电子和空穴在辐射复合前转移至Hg0.7Cd0.3Te的价带与导带上,导致CsPbBr3钙钛矿量子点薄膜的荧光强度下降;此外,钙钛矿电子空穴辐射复合发光的光子能量大于Hg0.7Cd0.3Te的带隙,部分荧光被Hg0.7Cd0.3Te吸收。最终CsPbBr3钙钛矿量子点薄膜异质结的荧光强度下降至单独CsPbBr3量子点薄膜强度的0.2倍,表明Type-I异质结中Hg0.7Cd0.3Te薄膜因界面的载流子传输导致其对CsPbBr3量子点薄膜荧光具有重要的调制作用。

     

    Abstract: Semiconductor heterostructure is one of the most important components of active optoelectronic devices. In this paper, the heterostructures of narrow-band gap Hg0.7Cd0.3Te semiconductor and wide-band gap CsPbBr3 semiconductor quantum dot films were constructed. Through the study, it was found that Type-I heterostructures were formed by the quantum dots and Hg0.7Cd0.3Te film. Some electrons and holes in CsPbBr3 perovskite quantum dot film were transferred to the valence band and conduction band of Hg0.7Cd0.3Te before radiation recombination, resulting in the decrease of fluorescence intensity of CsPbBr3 perovskite quantum dot film. In addition, the photon radiation energy of perovskite was greater than the band gap of Hg0.7Cd0.3Te, and part of the fluorescence was absorbed by Hg0.7Cd0.3Te. Finally, the fluorescence intensity of CsPbBr3 perovskite quantum dots film heterostructure decreased to 0.2 times that of CsPbBr3 quantum dots film alone, indicating that Hg0.7Cd0.3Te film in Type-I heterostructures had an important modulation effect on fluorescence of CsPbBr3 quantum dots film due to carrier transport at the interface.

     

/

返回文章
返回