高级检索
王寅,王首亮,陈灵. 共沉淀法制备LiNi0.5Co0.2Mn0.3O2前驱体搅拌釜反应器的CFD模拟[J]. 应用技术学报,2022,22(3):242-249+255.. DOI: 10.3969/j.issn.2096-3424.2022.03.009
引用本文: 王寅,王首亮,陈灵. 共沉淀法制备LiNi0.5Co0.2Mn0.3O2前驱体搅拌釜反应器的CFD模拟[J]. 应用技术学报,2022,22(3):242-249+255.. DOI: 10.3969/j.issn.2096-3424.2022.03.009
WANG Yin, WANG Shouliang, CHEN Ling. CFD Simulation of Stirring Tank Reactor for Production of LiNi0.5Co0.2Mn0.3O2 by Co-Prcipitation Method[J]. Journal of Technology, 2022, 22(3): 242-249, 255. DOI: 10.3969/j.issn.2096-3424.2022.03.009
Citation: WANG Yin, WANG Shouliang, CHEN Ling. CFD Simulation of Stirring Tank Reactor for Production of LiNi0.5Co0.2Mn0.3O2 by Co-Prcipitation Method[J]. Journal of Technology, 2022, 22(3): 242-249, 255. DOI: 10.3969/j.issn.2096-3424.2022.03.009

共沉淀法制备LiNi0.5Co0.2Mn0.3O2前驱体搅拌釜反应器的CFD模拟

CFD Simulation of Stirring Tank Reactor for Production of LiNi0.5Co0.2Mn0.3O2 by Co-Prcipitation Method

  • 摘要: LiNi0.5Co0.2Mn0.3O2材料具有稳定性好、高容量和低成本等优势,成为目前广泛使用的正极材料之一。LiNi0.5Co0.2Mn0.3O2前驱体的制备过程通常利用共沉淀反应生产,在此过程中容易出现颗粒团聚和循环“死区”等现象,导致前驱体颗粒的均匀性和批次稳定性较差等问题。采用计算流体动力学(computational fluid dynamics,CFD)技术研究了桨叶类型、搅拌速度和桨叶离底高度对反应釜流场内速度矢量分布、湍动能分布以及功率消耗的影响。结果表明,当选用锚框式搅拌桨(AF桨)、置于反应釜内的离底高度为0.10HH为模型高度)且转速为900 r/min时,釜内流场中具有强度适中且均匀的速度矢量和湍动能分布,径向与轴向速度分布合理,有利于制备出粒径更加均匀稳定的LiNi0.5Co0.2Mn0.3O2前驱体颗粒。

     

    Abstract: LiNi0.5Co0.2Mn0.3O2 (NCM) ternary material has become one of the most widely used cathode materials attributed to its advantages of stability, high capacity and low cost. NCM materials are usually prepared by co-precipitation reaction, in which particle sedimentation and circulation “dead zone” problems may occur in the liquid phase reaction and results in poor uniformity and batch stability of the products. The effects of blade type, stirring speed and blade height on the velocity vector distribution in the flow field, turbulent kinetic energy distribution and power consumption were studied based on the computational fluid dynamics (CFD) simulation in this paper. The results show that when the anchor frame stirring paddle (AF propeller) is placed at a height of 0.10H (structure height) from the bottom and used at a speed of 900 r/min, the reactor has the most uniform velocity vector and turbulent kinetic energy distribution with suitable power loss, which are suitable for production of NCM precursors with more evenly distributed and better electrochemical performance.

     

/

返回文章
返回