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万传云,陈晓戈. 锂离子电池用石墨烯改性硅负极材料的研究进展[J]. 应用技术学报,2022,22(4):330-336.. DOI: 10.3969/j.issn.2096-3424.2022.04.006
引用本文: 万传云,陈晓戈. 锂离子电池用石墨烯改性硅负极材料的研究进展[J]. 应用技术学报,2022,22(4):330-336.. DOI: 10.3969/j.issn.2096-3424.2022.04.006
WAN Chuanyun, CHEN Xiaoge. Progress of Graphene Modified Silicon Anode Materials for Lithium-Ion Batteries[J]. Journal of Technology, 2022, 22(4): 330-336. DOI: 10.3969/j.issn.2096-3424.2022.04.006
Citation: WAN Chuanyun, CHEN Xiaoge. Progress of Graphene Modified Silicon Anode Materials for Lithium-Ion Batteries[J]. Journal of Technology, 2022, 22(4): 330-336. DOI: 10.3969/j.issn.2096-3424.2022.04.006

锂离子电池用石墨烯改性硅负极材料的研究进展

Progress of Graphene Modified Silicon Anode Materials for Lithium-Ion Batteries

  • 摘要: 拥有高储锂能力的硅被认为是最具前途的锂离子电池负极材料之一。然而,在锂离子电池的充放电过程中,硅的体积变化较大(>300%)而且导电能力有限,导致硅电极的容量衰减。石墨烯是一种高比表面积、高导电性能和化学/机械稳定性优良的二维材料,其在提高硅材料导电性及改善锂离子电池的使用性能方面有很多优势。介绍了石墨烯在提高硅电极的容量及电极寿命方面的石墨烯改性硅材料的制备方法及材料性能,并对不同制备方法进行了比较,展望了硅/石墨烯复合材料的发展方向。

     

    Abstract: Silicon has a high lithium storage capacity, and it is considered by the market to be one of the most promising anode materials for lithium-ion batteries. However, in the process of charging and discharging lithium-ion batteries, the volume of silicon changes significantly (>300%) Moreover, the conductivity is limited, which causes the capacity of the silicon electrode to decrease. Graphene is a two-dimensional material with high specific surface area, high electrical conductivity and excellent chemical/mechanical stability. It has many advantages in improving the conductivity of silicon materials and improving the performance of lithium-ion batteries. The preparation methods and material properties of graphene-modified silicon materials for improving the capacity and electrode life of silicon electrodes are reviewed and compared. The development of silicon/graphene composite materials is prospected.

     

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