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李侃,张宏波. 西南某铅锌冶炼废渣堆放场地周边土壤重金属污染特征与风险评价[J]. 应用技术学报,2024,24(2):140-152.. DOI: 10.3969/j.issn.2096-3424.2022.097
引用本文: 李侃,张宏波. 西南某铅锌冶炼废渣堆放场地周边土壤重金属污染特征与风险评价[J]. 应用技术学报,2024,24(2):140-152.. DOI: 10.3969/j.issn.2096-3424.2022.097
LI Kan, ZHANG Hongbo. Pollution characteristics and risk assessment of heavy metals in soil around a lead-zinc smelting waste residue dump in southwest China[J]. Journal of Technology, 2024, 24(2): 140-152. DOI: 10.3969/j.issn.2096-3424.2022.097
Citation: LI Kan, ZHANG Hongbo. Pollution characteristics and risk assessment of heavy metals in soil around a lead-zinc smelting waste residue dump in southwest China[J]. Journal of Technology, 2024, 24(2): 140-152. DOI: 10.3969/j.issn.2096-3424.2022.097

西南某铅锌冶炼废渣堆放场地周边土壤重金属污染特征与风险评价

Pollution characteristics and risk assessment of heavy metals in soil around a lead-zinc smelting waste residue dump in southwest China

  • 摘要: 为探究西南某铅锌废堆渣场地及其周围土壤中重金属空间分布特征和生态风险,以西南某废弃铅锌冶炼废渣堆放场地为研究目标,通过检测其土壤中As、Pb、Zn、Cd、Cr、Cu、Hg、Ni共8种元素,概括其空间分布特征,分析重金属存在形态对其迁移与渗透的影响,并采用多个污染评价方法对该废渣堆放场的重金属状况进行污染风险评估。结果表明:堆渣场地重金属元素分布与地表径流方向一致,且向深层土壤渗透;As、Cd、Cu已很难再以离子形态随地表径流进一步迁移,而Pb、Zn目前仍具有较大的离子迁移性能,仍会进一步向周边及深层土壤扩散;按照综合污染指数评价上层堆渣区属于重污染,污染元素主要来源于As;同时As、Cd含量表现出极强的生态毒性,使该区域存在很强的生态风险。研究结果为该区域土壤的进一步修复提供了理论依据和参考。

     

    Abstract: In order to explore the spatial distribution characteristics and ecological risks of heavy metals in the slag dump site and the surrounding soil, 8 elements including As, Cd, Cr, Cu, Hg, Ni, Pb and Zn in the soil were detected in a waste lead and zinc smelting slag dump site in southwest China. Spatial distribution characteristics of heavy metals were summarized, the impacts of existing forms on their migration and infiltration were analyzed, and the risks of their pollution status were assessed by using a variety of assessment methods. The results showed that the distribution of heavy metals in the slag dump site was consistent with the direction of surface runoff, and they penetrated into deep soil. It is difficult for As, Cd and Cu to further migrate along the surface runoff in the form of ions, while Pb and Zn still have relatively large ion mobility, and will further diffuse to the surrounding and deep soil. According to the comprehensive pollution index, the upper slag stacking area is seriously polluted, and the pollution elements mainly come from As. At the same time, the contents of As and Cd showed extremely strong ecological toxicity, which makes the region exhibits a strong ecological risk. The research results provide a theoretical basis and reference for further soil remediation in this region.

     

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