高级检索

燃料电池金属双极板表面氮(碳)基复合涂层的改性研究综述

A review on modification research of nitrogen (carbon) based composite coatings on the surface of fuel cell metallic bipolar plates

  • 摘要: 近年来,兼具高耐蚀性、高导电性和优异水管理能力的氮(碳)基复合涂层是氢能及燃料电池领域的热门话题,尤其是其对金属双极板在严苛环境下的防护行为备受关注。本文分析了金属双极板性能衰减与腐蚀失效的原因,研究发现涂层的微观相结构与组分分布是影响其实现长效服役的主要因素,而涂层的微观结构由其制备工艺决定。系统讨论了制备工艺(包括沉积技术、反应气源、组分调控和基体材料等)和服役环境(包括酸性介质、电位波动、多场耦合工况等)对氮(碳)基复合涂层耐蚀性与导电性的影响规律。剖析了碳相引入诱导纳米晶/非晶复合结构形成的内在机理,归纳了非晶相“密封”效应与导电网络协同保护的机制,指出了金属双极板涂层作为关键改性材料仍需解决的问题及未来的研究趋势。

     

    Abstract: In recent years, nitrogen (carbon) based composite coatings with high corrosion resistance, high conductivity and excellent water management ability have become a hot topic in the field of hydrogen energy and fuel cells, especially their protective behavior against metal bipolar plates under extreme operation conditions. In this paper, the causes of performance degradation and corrosion failure of metal bipolar plate were analyzed. It was found that the microstructure and component distribution of the coating were the main factors affecting its long-term service, and the microstructure of the coating was determined by its deposition process. Then, the effects of deposition parameters (including deposition technology, reaction gas source, component control and matrix material) and service environment (including acid medium, potential fluctuation, multi field coupling conditions) on the corrosion resistance and conductivity of nitrogen (carbon) based composite coatings were systematically discussed. The internal mechanism of the formation of nanocrystalline/amorphous composite structure induced by the introduction of carbon phase was analyzed, and the mechanism of cooperative protection between the "sealing" effect of amorphous phase and conductive network was summarized. Finally, the problems that need to be solved and the future research trend of metal bipolar plate coating as a key modified material are pointed out.

     

/

返回文章
返回