The Catalytic Properties of Mn-Based Metal-Organic Framework for Benzylalcohol Oxidation

SHI Junxia; CUI Penghui; ZHANG Jianyong

doi:10.3969/j.issn.2096-3424.2019.02.006

SHI Junxia, CUI Penghui, ZHANG Jianyong. The Catalytic Properties of Mn-Based Metal-Organic Framework for Benzylalcohol Oxidation[J]. Journal of Technology, 2019, 19(2): 136-139, 151. DOI: 10.3969/j.issn.2096-3424.2019.02.006

Citation:

The Catalytic Properties of Mn-Based Metal-Organic Framework for Benzylalcohol Oxidation

Graphical Abstract

Graphical Abstract

Abstract

Abstract

The Mn-based metal-organic framework (Mn-MOF) material was successfully synthesized by reaction of dihydroxyterephthalic acid and Mn²⁺ ions under solvothermal condition. The synthesized Mn-based MOF was characterized by infrared spectroscopy (IR), powder X-ray diffraction (PXRD), and N₂ absorption-desorption (BET). More importantly, the catalytic measurements show that Mn-MOF was a good catalyst for benzylalcohol oxidation under air conditions and still gives 94% conversion in 6 h after 10 catalytic cycles, implying its good potential application as heterocatalyst.