环境响应型潜香体设计与修饰研究进展

胡静; 刘明

doi:10.3969/j.issn.2096-3424.2024.01.011

环境响应型潜香体设计与修饰研究进展

doi: 10.3969/j.issn.2096-3424.2024.01.011

胡静,
刘明^,

上海应用技术大学香料香精化妆品学部, 上海 201418

基金项目: 国家自然科学基金项目（22078196、22278268和22208218）；上海市自然科学基金项目（22ZR1460400）；上海应用技术大学引进人才基金项目（YJ2022-16）；上海应用技术协同创新基金项目（XTCX2023-07）资助

详细信息

作者简介:
胡静：胡　静（1982-），女，教授，博士，主要研究方向为香料香精包覆及应用，潜香体制备及气味调控研究。E-mail：hujing@sit.edu.cn

通讯作者:
刘　明（1993-），男，讲师，博士，硕导，主要研究方向为潜香体制备与控释性能研究。E-mail：mingliu@sit.edu.cn

中图分类号: O69
计量
- 文章访问数: 65
- HTML全文浏览量: 37
- PDF下载量: 8
- 被引次数: 0
出版历程
- 收稿日期: 2023-10-31
- 网络出版日期: 2024-01-26
- 刊出日期: 2024-03-30

Advances in design and modification of environmentally responsive profragrances

HU Jing,
LIU Ming^,

School of Perfume and Aroma Technology, Shanghai Institute of Technology, Shanghai 201418, China

摘要

摘要: 潜香体是基于环境响应型共价键而将香料分子与非挥发性基质键连形成的新型香料控释体系，其能够在环境条件下实现香料分子的主动控释，从而延长香料留香时间。该类前体物质使得日益精细化和功能化的高端香料发展趋势成为可能，由此导致基于环境控制的潜香体体系受到广泛关注。综述了基本的反应型潜香体，重点介绍光照控释型、水解控释型以及生物酶控释型潜香体的研究进展；介绍了新型的胶囊潜香体和聚合物潜香体；并对潜香体进一步的开发与应用进行了总结与展望。
- 环境响应型 /
- 香料 /
- 潜香体 /
- 控制释放
Abstract: As a novel controllable fragrance release system formed by conjugating fragrant molecules with non-volatile substrates based on environmentally responsive covalent bonds, profragrance can realize active-controllable release of fragrant molecules under environmental conditions, thus prolonging fragrance retention time. This type of precursor substance makes it possible for the increasingly refined and functional development trend of high-end fragrances, which has led to widespread attention to the environmentally responsive controllable profragrances. In this paper, the basic reactive profragrances were reviewed, with emphasis on the recent advances in photo controllable release system, hydrolysis controllable release system and enzyme controllable release system. In addition, novel encapsulated and polymeric profragrances were introduced. Finally, new insights into further development and application of profragrances were summarized.
- environmentally responsive /
- fragrances /
- profragrances /
- controllable release

HTML全文

图 1 环境响应型潜香体及其香料控释机理^[21]

Figure 1. Environmentally responsive profragrances and the mechanism of controllable fragrance release^[21]

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图 2 基于不同光保护基团的光响应型潜香体

注：1为丙烯酸酯^[22]，2为苯甲酸酯^[23]，3为咕吨酸酯^[24]，4为2-硝基苄基衍生物^[25-26]，5为α-酮酯^[27]，6为烷基苯酮^[28]，7为蒽醌^[29]，8为环形缩醛类^[30]

Figure 2. Photoresponsive profragrances based on different photo-protecting groups

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图 3 基于α-酮酯的光响应型潜香体及其光裂解反应香料控释机理^[27]

Figure 3. α-oxoacetates-based photoresponsive profragrances and the mechanism of photofragmentation for the controllable fragrance release^[27]

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图 4 基于各种不同水解机理的水解型潜香体

注：9为迈克尔加成型^[31]，10为缩醛型^[32]，11为缩醛胺型^[33]，12为邻键参与型^[34]

Figure 4. Hydrolytically responsive profragrances based on different hydrolytic mechanism

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图 5 阴阳离子液体混合型潜香体的化学结构^[35]

Figure 5. Chemical structure of anion and cation liquid-based profragrances^[35]

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图 6 基于吡啶盐的潜香体及其水解反应香料控释机理^[36]

Figure 6. Profragrances on the basis of quaternary pyridinium salts and the mechanism of hydrolysis for the controllable fragrance release^[36]

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图 7 基于脂肪酶和光照双重响应构建的潜香体及其控释机理^[37]

Figure 7. Construction of profragrances based on the double response of lipase and light and the mechanism for controllable fragrance release^[37]

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图 8 基于自氧化机理构建的乙烯醚型潜香体及其醛类香料分子的控释^[39]

Figure 8. Autooxidation-based profragrances for controllable fragment aldehydes release^[39]

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图 9 基于聚顺丁烯二酸酐制备的聚合物潜香体^[42]

Figure 9. Poly (maleic anhydride)-based polymeric profragrances^[42]

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图 10 基于壳聚糖制备的聚合物潜香体^[43]

Figure 10. The fabrication of chitosan-based polymeric profragrances^[43]

下载: 全尺寸图片幻灯片

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